Monday, October 27, 2014

3.3.1 Discuss the similarities and differences in the chemical properties of elements in the same group.

Group 1
  • Group 1 metals = Alkali Metals
  • share similarities and differences in their chemical properties.
  • reactive, especially with air and water 
  • often stored in paraffin to avoid contact with air
  • react quite vigorously with water
  • ex) lithium with water will most likely lead to a slow reaction
  • ex) caesium with water is almost an explosion
  • reactivity increases down the group because of decreasing electrostatic attraction to outer shells, therefore electrons can be lost easily.
  • good reducing agents because they donate electrons
  • the reaction is exothermic (releases energy) 
  • metal hydroxide and hydrogen
  • first two float
  • might ignite and produce a flame (ex) potassium = violet flame 
Alkali Metals reactions with water
  • A = generic alkali
  • 2A (s) + 2H2O (l) → 2AOH (aq) + H2(g)
  • Alkali metal + Water →Metal hydroxide + hydrogen
  • We can also write this reaction in its ionic form, as alkali metals form ionic compounds:
  • 2A (s) + 2H2O (l) →2A+ (aq) + 2OH- (aq) + H2 (g)

Group 7: Halogens
  • 7 outer electrons
  • reactivity decreases down the group because the distance between the nucleus and outer-electron increases as you go down the group
  • are good oxidizing agents because they accept electrons easily
Halogens reaction with alkalis
  • A = generic alkali
  • Ha = generic halogen
  • Halogen reaction with alkali's
  • 2A (s) + HA2→2AH2 (s) = 2KBr +Cl2 → 2KCl +Br2 
  • chlorine = gaseous state
  • bromine = liquid state
  • iodine = solid state 
  • after reaction known as a halide
  • produce a salt
  • we often call this “Displacement reactions”
Group 0/8 : Nobel Gases
  • colorless gases
  • monoatomic 
  • very unreactive because they do not gain or lose electrons
  • stable octect (full outer shell)

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